C-H activation in strongly acidic media. The co-catalytic effect of the reaction medium.
نویسندگان
چکیده
Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between Pt(II)(bpym)Cl(2) (bpym = 2,2'-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.
منابع مشابه
Ethanol electrooxidation on the Co@Pt core-shell nanoparticles modified carbon-ceramic electrode in acidic and alkaline media
In this study, the electrocatalytic activity of the Co@Pt core-shell nanoparticles toward the ethanol oxidation reaction has been investigated by cyclic voltammetry and chronoamperometry in acidic and alkaline media in details. The physicochemical data obtained in alkaline solution are compared to those in acidic solution. The obtained results demonstrate that while in the both media Co@Pt core...
متن کاملSPECTROPHOTOMETRIC REACTION RATE METHOD FOR THE DETERMINATION OF NITRITE BY CATALYTIC ACTION ON NILE BLUE A BROMATE REACTION
A kinetic method developed for the determination of ultra-trace amounts of nitrite based on its catalytic effect on the reaction between potassium bromate and Nile blue A in strongly acidic media is reported. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of Nile blue A at 645 nm by the fixed-time method. The decrease in absorbance during the first...
متن کاملCatalytic Oxidative-Extractive Deep Desulfurization of Diesel Fuel by N-methyl-2-pyrrolidone-Based Protic Acidic Ionic Liquids (PAILs)
Inexpensive and low-viscosity Protic Acidic Ionic Liquids (PAILs) of N-metheyl-2-pyrrolidone formate, acetate, and propionate abbreviated as [Hnmp][HCOO], [Hnmp][CH3COO] and [Hnmp][CH3CH2COO] respectively, were prepared and characterized by FT-IR and H-NMR. Deep oxidative and extractive desulfurization of a simulated oil and a real diesel containing 1000 ppm...
متن کاملThe green synthesis of pyrano[3,2-c]quinoline-2,5-dione derivatives catalyzed by acidic ionic liquid under ultrasound irradiation
Abstract-A novel and efficient method has been developed for the synthesis of pyrano[3,2-c]quinoline-2,5-dione derivatives by the convenient ultrasound-mediated condensation of 4-hydroxyquinolin-2-one with Meldrum’s acid and aldehydes in the presence of a catalytic amount of [HMIm]HSO4 as a green, efficient and reusable acidic ionic liquid medium. The stability of the ionic liquid during the re...
متن کاملRapid Determination of Chromium (M)lli Natural Water and Industrial Effluents Using Kinetic Speetrophotometric Method
A new simple arid rapid catalytic kinetic method for determination of trace amounts of chromium (110 isdescribed. The method is based on the catalytic effect of chromium (III) on the reduction of Methylene blue byascorbic acid in acidic media. The reaction monitored smectrophotomenically by measuring the decrease ofabsorbance at 664 nm at 25 C. The fixed-time method was used for the first 300 s...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 17 شماره
صفحات -
تاریخ انتشار 2009